Two‐Component Liquid Crystals as Chiral Reaction Media: Highly Enantioselective Photodimerization of an Anthracene Derivative Driven by the Ordered Microenvironment | Zendy

Ishida Yasuhiro | Zendy; Kai Yukiko | Zendy; Kato Syunya | Zendy; Misawa Aya | Zendy; Amano Sayaka | Zendy; Matsuoka Yuki | Zendy; Saigo Kazuhiko | Zendy

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Two‐Component Liquid Crystals as Chiral Reaction Media: Highly Enantioselective Photodimerization of an Anthracene Derivative Driven by the Ordered Microenvironment

Author(s) -

Ishida Yasuhiro,

Kai Yukiko,

Kato Syunya,

Misawa Aya,

Amano Sayaka,

Matsuoka Yuki,

Saigo Kazuhiko

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200803242

Subject(s) - anthracene , enantioselective synthesis , derivative (finance) , amphiphile , component (thermodynamics) , chemistry , alcohol , organic chemistry , catalysis , physics , polymer , copolymer , financial economics , economics , thermodynamics

Tailored to the reaction : Within a liquid‐crystalline matrix provided by a chiral amphiphilic amino alcohol, the photodimerization of an anthracenecarboxylic acid proceeds with high probability and with excellent regio‐, diastereo‐, and enantioselectivities (up to 81 % ee ).

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