A Water Soluble Diruthenium–Gold Organometallic Microgel | Zendy

Serrano Ruiz Manuel | Zendy; Romerosa Antonio | Zendy; SierraMartin Benjamín | Zendy; FernandezBarbero Antonio | Zendy

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A Water Soluble Diruthenium–Gold Organometallic Microgel

Author(s) -

Serrano Ruiz Manuel,

Romerosa Antonio,

SierraMartin Benjamín,

FernandezBarbero Antonio

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200803232

Subject(s) - cyclopentadienyl complex , chemistry , polymer chemistry , orange (colour) , polymer , transition metal , bridging (networking) , ruthenium , metal , water soluble , ligand (biochemistry) , photochemistry , organic chemistry , catalysis , computer network , biochemistry , receptor , food science , computer science

Bridging the gap : Two metal‐containing moieties, [CpRuCNRuCp] + and [Au(CN) 4 ] − , are bridged through a pta ligand in the P,N coordination mode in a water‐soluble, air‐stable heterobimetallic coordination polymer (see picture, Au orange, Ru turquoise, C gray, N blue, P purple). This complex exhibits gel‐like behavior in water, specifically a thermally controlled volume transition. pta=1,3,5‐triaza‐7‐phosphaadamantane, Cp=cyclopentadienyl.

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