Intramolecular Activation of a Disila[2]molybdenocenophanedihydride: Synthesis and Structure of a [1],[1]Metalloarenophane | Zendy

Braunschweig Holger | Zendy; Gross Manuela | Zendy; Radacki Krzysztof | Zendy; Rothgaengel Christian | Zendy

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Intramolecular Activation of a Disila[2]molybdenocenophanedihydride: Synthesis and Structure of a [1],[1]Metalloarenophane

Author(s) -

Braunschweig Holger,

Gross Manuela,

Radacki Krzysztof,

Rothgaengel Christian

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200803223

Subject(s) - intramolecular force , cyclopentadienyl complex , chemistry , photochemistry , polymer chemistry , crystallography , stereochemistry , catalysis , organic chemistry

Breaking bridges : Disila[2]molybdenocenophanedihydride was synthesized by dilithiation of 1,2‐bis(cyclopentadienyl)tetramethyldisilane and subsequent reaction with MoCl 5 in the presence of NaBH 4 . The photochemical conversion of the ansa complex leads to a highly unusual, twofold bridged [1],[1]molybdenocenophane (see scheme; C black, H white, Si pink, Mo violet).

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