Premium
Aryllithium Compounds Bearing Alkoxycarbonyl Groups: Generation and Reactions Using a Microflow System
Author(s) -
Nagaki Aiichiro,
Kim Heejin,
Yoshida Junichi
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200803205
Subject(s) - bearing (navigation) , residence , residence time (fluid dynamics) , mixing (physics) , group (periodic table) , range (aeronautics) , chemistry , information flow , computer science , process engineering , organic chemistry , engineering , sociology , philosophy , physics , artificial intelligence , demography , geotechnical engineering , quantum mechanics , aerospace engineering , linguistics
Go with the flow : An effective method for the generation and reaction of aryllithium compounds bearing an alkoxycarbonyl group is developed using microflow systems with very short residence times together with fast mixing and efficient temperature control. A wide range of alkoxycarbonyl groups including ethoxycarbonyl and methoxycarbonyl groups are tolerant of the microflow conditions.