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A Palladium‐Catalyzed Dehydrogenative Diamination of Terminal Olefins
Author(s) -
Wang Bin,
Du Haifeng,
Shi Yian
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200803184
Subject(s) - amination , regioselectivity , palladium , allylic rearrangement , catalysis , chemistry , terminal (telecommunication) , combinatorial chemistry , organic chemistry , computer science , telecommunications
A dynamic diamination : The title transformation has been developed with diaziridine 1 as the nitrogen source (see scheme; dba= trans , trans ‐dibenzylideneacetone). The reaction proceeds through an allylic amination and subsequent cyclization, and a variety of terminal olefins can be effectively diaminated with high regioselectivity.