Filling the Cavity of Conjugated Carbazole Macrocycles with Graphene Molecules: Monolayers Formed by Physisorption Serve as a Surface for Pulsed Laser Deposition | Zendy

Schmaltz Bruno | Zendy; Rouhanipour Ali | Zendy; Räder Hans Joachim | Zendy; Pisula Wojciech | Zendy; Müllen Klaus | Zendy

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Filling the Cavity of Conjugated Carbazole Macrocycles with Graphene Molecules: Monolayers Formed by Physisorption Serve as a Surface for Pulsed Laser Deposition

Author(s) -

Schmaltz Bruno,

Rouhanipour Ali,

Räder Hans Joachim,

Pisula Wojciech,

Müllen Klaus

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200803156

Subject(s) - physisorption , monolayer , conjugated system , deposition (geology) , graphene , molecule , carbazole , materials science , nanotechnology , chemistry , photochemistry , organic chemistry , adsorption , geology , composite material , paleontology , sediment , polymer

Finding the middle ground : A 1:1 host–guest complex consisting of a hexa‐ peri ‐hexabenzocoronene molecule sitting in the middle of the free cavity of a giant π‐conjugated carbazole macrocycle has been obtained (see STM image). The complex has been prepared by physisorption of a monolayer of macrocycles followed by gas‐phase deposition of graphene molecules by pulsed laser deposition.

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