A Tailored Organometallic–Inorganic Hybrid Mesostructured Material: A Route to a Well‐Defined, Active, and Reusable Heterogeneous Iridium‐NHC Catalyst for H/D Exchange | Zendy

Maishal Tarun K. | Zendy; Alauzun Johan | Zendy; Basset JeanMarie | Zendy; Copéret Christophe | Zendy; Corriu Robert J. P. | Zendy; Jeanneau Erwan | Zendy; Mehdi Ahmad | Zendy; Reyé Catherine | Zendy; Veyre Laurent | Zendy; Thieuleux Chloé | Zendy

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A Tailored Organometallic–Inorganic Hybrid Mesostructured Material: A Route to a Well‐Defined, Active, and Reusable Heterogeneous Iridium‐NHC Catalyst for H/D Exchange

Author(s) -

Maishal Tarun K.,

Alauzun Johan,

Basset JeanMarie,

Copéret Christophe,

Corriu Robert J. P.,

Jeanneau Erwan,

Mehdi Ahmad,

Reyé Catherine,

Veyre Laurent,

Thieuleux Chloé

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200802956

Subject(s) - iridium , catalysis , organometallic chemistry , group 2 organometallic chemistry , chemistry , materials science , nanotechnology , organic chemistry , molecule

A tailored hybrid mesostructured material containing regularly distributed imidazolium units, and subsequent transformation of these imidazolium moieties into Ir‐NHC (NHC=N‐heterocyclic carbene) complexes via the formation of Ag‐NHC species in situ and further transmetalation with [{IrCp*Cl 2 } 2 ], gives a well‐defined, active, and reusable Ir‐NHC heterogeneous catalyst for H/D exchange reactions (see picture).

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