A Stereospecific Palladium‐Catalyzed Route to Monoalkyl Diazenes for Mild Allylic Reduction | Zendy

Movassaghi Mohammad | Zendy; Ahmad Omar K. | Zendy

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A Stereospecific Palladium‐Catalyzed Route to Monoalkyl Diazenes for Mild Allylic Reduction

Author(s) -

Movassaghi Mohammad,

Ahmad Omar K.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200802921

Subject(s) - stereospecificity , allylic rearrangement , electrophile , catalysis , chemistry , palladium , reduction (mathematics) , combinatorial chemistry , organic chemistry , mathematics , geometry

One step beyond : The first single‐step stereospecific transition‐metal‐catalyzed conversion of allylic electrophiles into monoalkyl diazenes is described. This synthesis of allylic monoalkyl diazenes offers a new strategy for asymmetric synthesis by the reduction of optically active substrates or the use of chiral catalyst systems. Sensitive substrates are reduced in a highly selective manner. Ar=2‐NO 2 C 6 H 4 .

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