Post‐Synthetic Modification of Tagged Metal–Organic Frameworks | Zendy

Burrows Andrew D. | Zendy; Frost Christopher G. | Zendy; Mahon Mary F. | Zendy; Richardson Christopher | Zendy

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Post‐Synthetic Modification of Tagged Metal–Organic Frameworks

Author(s) -

Burrows Andrew D.,

Frost Christopher G.,

Mahon Mary F.,

Richardson Christopher

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200802908

Subject(s) - aldehyde , hydrazone , metal organic framework , chemistry , zinc , metal , combinatorial chemistry , organic chemistry , polymer chemistry , catalysis , adsorption

Playing tag with MOFs : Zinc metal–organic frameworks with pendant aldehyde and methoxy groups are prepared. The aldehyde‐tagged MOF takes up 2,4‐dinitrophenylhydrazine, reacting to form a hydrazone‐functionalized MOF which is crystallographically characterized. Use of both aldehyde‐ and methoxy‐functionalized dicarboxylates leads to MOFs containing both ligands, of which the aldehyde groups can be selectively reacted.

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