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Post‐Synthetic Modification of Tagged Metal–Organic Frameworks
Author(s) -
Burrows Andrew D.,
Frost Christopher G.,
Mahon Mary F.,
Richardson Christopher
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200802908
Subject(s) - aldehyde , hydrazone , metal organic framework , chemistry , zinc , metal , combinatorial chemistry , organic chemistry , polymer chemistry , catalysis , adsorption
Playing tag with MOFs : Zinc metal–organic frameworks with pendant aldehyde and methoxy groups are prepared. The aldehyde‐tagged MOF takes up 2,4‐dinitrophenylhydrazine, reacting to form a hydrazone‐functionalized MOF which is crystallographically characterized. Use of both aldehyde‐ and methoxy‐functionalized dicarboxylates leads to MOFs containing both ligands, of which the aldehyde groups can be selectively reacted.