An Iron(II) Spin‐Crossover Complex with a 70 K Wide Thermal Hysteresis Loop | Zendy

Weber Birgit | Zendy; Bauer Wolfgang | Zendy; Obel Jaroslava | Zendy

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An Iron(II) Spin‐Crossover Complex with a 70 K Wide Thermal Hysteresis Loop

Author(s) -

Weber Birgit,

Bauer Wolfgang,

Obel Jaroslava

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200802806

Subject(s) - thermal hysteresis , spin crossover , hysteresis , crossover , loop (graph theory) , intermolecular force , spin (aerodynamics) , thermal , hydrogen bond , condensed matter physics , materials science , computer science , physics , chemical physics , chemistry , thermodynamics , molecule , mathematics , combinatorics , quantum mechanics , phase transition , artificial intelligence

Going loopy : A new iron(II) spin‐crossover complex displays a 70 K wide thermal hysteresis loop, which can be explained by an intermolecular 2D network of hydrogen bonds. This is the first example of a spin‐crossover complex with wide hysteresis arising from a hydrogen‐bond network; it displays the widest hysteresis to date for a structurally characterized complex.

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