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Reactive Intermediates in Oxygenation Reactions with Mononuclear Nonheme Iron Catalysts
Author(s) -
Yoon Jihae,
Wilson Samuel A.,
Jang Yu Kyeong,
Seo Mi Sook,
Nehru Kasi,
Hedman Britt,
Hodgson Keith O.,
Bill Eckhard,
Solomon Edward I.,
Nam Wonwoo
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200802672
Subject(s) - catalysis , reactivity (psychology) , chemistry , hydrogen atom abstraction , medicinal chemistry , oxygen atom , reaction mechanism , primary (astronomy) , diamine , hydrogen , photochemistry , polymer chemistry , organic chemistry , molecule , medicine , physics , alternative medicine , pathology , astronomy
An advanced intermediate : A nonheme iron(IV) oxo complex [Fe IV (O)(bqen)(L)] n + (bqen= N , N ′‐dimethyl‐ N , N ′‐bis(8‐quinolyl)ethane‐1,2‐diamine, L=CH 3 CN or CF 3 SO 3 − ) activates the CH bonds of alkanes and alcohols by a hydrogen‐atom abstraction mechanism. The catalytic oxidation of these species is proposed to occur through a nonheme iron(V) oxo species, with a high reactivity in oxidation reactions (see picture).