Reactive Intermediates in Oxygenation Reactions with Mononuclear Nonheme Iron Catalysts | Zendy

Yoon Jihae | Zendy; Wilson Samuel A. | Zendy; Jang Yu Kyeong | Zendy; Seo Mi Sook | Zendy; Nehru Kasi | Zendy; Hedman Britt | Zendy; Hodgson Keith O. | Zendy; Bill Eckhard | Zendy; Solomon Edward I. | Zendy; Nam Wonwoo | Zendy

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Reactive Intermediates in Oxygenation Reactions with Mononuclear Nonheme Iron Catalysts

Author(s) -

Yoon Jihae,

Wilson Samuel A.,

Jang Yu Kyeong,

Seo Mi Sook,

Nehru Kasi,

Hedman Britt,

Hodgson Keith O.,

Bill Eckhard,

Solomon Edward I.,

Nam Wonwoo

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200802672

Subject(s) - catalysis , reactivity (psychology) , chemistry , hydrogen atom abstraction , medicinal chemistry , oxygen atom , reaction mechanism , primary (astronomy) , diamine , hydrogen , photochemistry , polymer chemistry , organic chemistry , molecule , medicine , physics , alternative medicine , pathology , astronomy

An advanced intermediate : A nonheme iron(IV) oxo complex [Fe IV (O)(bqen)(L)] n + (bqen= N , N ′‐dimethyl‐ N , N ′‐bis(8‐quinolyl)ethane‐1,2‐diamine, L=CH 3 CN or CF 3 SO 3 − ) activates the CH bonds of alkanes and alcohols by a hydrogen‐atom abstraction mechanism. The catalytic oxidation of these species is proposed to occur through a nonheme iron(V) oxo species, with a high reactivity in oxidation reactions (see picture).

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