Site‐Selective Fabrication of Two‐Dimensional Fullerene Arrays by Using a Supramolecular Template at the Liquid‐Solid Interface | Zendy

Li Min | Zendy; Deng Ke | Zendy; Lei ShengBin | Zendy; Yang YanLian | Zendy; Wang TaiShan | Zendy; Shen YongTao | Zendy; Wang ChunRu | Zendy; Zeng QingDao | Zendy; Wang Chen | Zendy

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Site‐Selective Fabrication of Two‐Dimensional Fullerene Arrays by Using a Supramolecular Template at the Liquid‐Solid Interface

Author(s) -

Li Min,

Deng Ke,

Lei ShengBin,

Yang YanLian,

Wang TaiShan,

Shen YongTao,

Wang ChunRu,

Zeng QingDao,

Wang Chen

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200802518

Subject(s) - fullerene , graphite , interface (matter) , azobenzene , supramolecular chemistry , materials science , fabrication , derivative (finance) , nanotechnology , porosity , combinatorial chemistry , chemistry , molecule , organic chemistry , composite material , medicine , gibbs isotherm , alternative medicine , pathology , financial economics , economics

A selective invitation : A 2D hydrogen‐bonded porous network formed by an azobenzene derivative (NN4 A) contains two different types of cavities and is shown to selectively accommodate fullerenes C 80 and Sc 3 N§C 80 (see picture). Highly ordered fullerene arrays are constructed at the liquid–solid interface of graphite by coadsorption of fullerenes and NN4 A. While C 60 occupies both types of cavity, C 80 and Sc 3 N§C 80 are only immobilized in one cavity type.

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