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PO 4 3− ‐Mediated Polyoxometalate Supercluster Assembly
Author(s) -
Fang Xikui,
Kögerler Paul
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200802491
Subject(s) - polyoxometalate , supercluster (genetic) , ion , crystallography , chemistry , component (thermodynamics) , nanotechnology , materials science , physics , catalysis , organic chemistry , biochemistry , phylogenetics , thermodynamics , gene
Small anion, big task : The assembly of a ten‐component, heterochiral polyoxometalate aggregate, driven by the templating effect of a single phosphate anion, proceeds through a coordination‐number‐controlled formation route from three dimeric Dawson anion based magnetic building blocks.