Monitoring Biomimetic Platinum Nanocluster Formation Using Mass Spectrometry and Cluster‐Dependent H 2  Production | Zendy

Kang Sebyung | Zendy; Lucon Janice | Zendy; Varpness Zachary B. | Zendy; Liepold Lars | Zendy; Uchida Masaki | Zendy; Willits Debbie | Zendy; Young Mark | Zendy; Douglas Trevor | Zendy

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Monitoring Biomimetic Platinum Nanocluster Formation Using Mass Spectrometry and Cluster‐Dependent H 2 Production

Author(s) -

Kang Sebyung,

Lucon Janice,

Varpness Zachary B.,

Liepold Lars,

Uchida Masaki,

Willits Debbie,

Young Mark,

Douglas Trevor

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200802481

Subject(s) - triethanolamine , iridium , mass spectrometry , platinum , chemistry , cluster (spacecraft) , catalysis , photochemistry , analytical chemistry (journal) , chromatography , organic chemistry , computer science , programming language

Matter of size : Platinum nanocluster formation inside protein cages (LiDps protein) was monitored by noncovalent mass spectrometry. The Pt clusters catalyze hydrogen formation in presence of an iridium photosensitizer (PS; see scheme, TEOA=triethanolamine), and their catalytic activity depends on the cluster size.

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