A Polymer‐Bound Chiral Template for Enantioselective Photochemical Reactions | Zendy

Breitenlechner Stefan | Zendy; Bach Thorsten | Zendy

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A Polymer‐Bound Chiral Template for Enantioselective Photochemical Reactions

Author(s) -

Breitenlechner Stefan,

Bach Thorsten

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200802479

Subject(s) - enantioselective synthesis , template , linker , chemistry , content (measure theory) , combinatorial chemistry , computer science , catalysis , organic chemistry , nanotechnology , materials science , mathematics , mathematical analysis , operating system

A happy couple : A chiral complexing agent was modified with an ω‐hydroxyalkyl linker and immobilized on a Wang resin and on a methoxypolyethylene glycol (MPEG 2000). The immobilized templates 1 served in an enantioselective photochemical reaction with impressive selectivity (e.r. 92:8 to 96:4) and stability over several cycles.

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