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A Polymer‐Bound Chiral Template for Enantioselective Photochemical Reactions
Author(s) -
Breitenlechner Stefan,
Bach Thorsten
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200802479
Subject(s) - enantioselective synthesis , template , linker , chemistry , content (measure theory) , combinatorial chemistry , computer science , catalysis , organic chemistry , nanotechnology , materials science , mathematics , mathematical analysis , operating system
A happy couple : A chiral complexing agent was modified with an ω‐hydroxyalkyl linker and immobilized on a Wang resin and on a methoxypolyethylene glycol (MPEG 2000). The immobilized templates 1 served in an enantioselective photochemical reaction with impressive selectivity (e.r. 92:8 to 96:4) and stability over several cycles.