[Sn 17 {GaCl(ddp)} 4 ]: A High‐Nuclearity Metalloid Tin Cluster Trapped by Electrophilic Gallium Ligands | Zendy

Prabusankar Ganesan | Zendy; Kempter Andreas | Zendy; Gemel Christian | Zendy; Schröter MarieKatrin | Zendy; Fischer Roland A. | Zendy

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[Sn 17 {GaCl(ddp)} 4 ]: A High‐Nuclearity Metalloid Tin Cluster Trapped by Electrophilic Gallium Ligands

Author(s) -

Prabusankar Ganesan,

Kempter Andreas,

Gemel Christian,

Schröter MarieKatrin,

Fischer Roland A.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200802470

Subject(s) - gallium , metalloid , electrophile , tin , cluster (spacecraft) , chemistry , main group element , inorganic chemistry , metal , crystallography , transition metal , organic chemistry , catalysis , computer science , programming language

The reduction of SnCl 2 by the low‐valent gallium(I) β‐diketiminate Ga I (ddp) gives the title complex, which is best described as a Zintl‐type anionic [Sn 17 ] 4− cluster stabilized by an electrophilic shell of gallium ligands. This reaction could represent a new concept for the synthesis of metalloid main‐group clusters. ddp=HC(CMeNC 6 H 3 ‐2,6‐ i Pr 2 ) 2 .

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