Intramolecular Huisgen‐Type Cyclization of Platinum‐Bound Pyrylium Ions with Alkenes and Subsequent Insertion into a Benzylic CH Bond | Zendy

Oh Chang Ho | Zendy; Lee Ji Ho | Zendy; Lee Su Jin | Zendy; Kim Jae Il | Zendy; Hong Chang Seop | Zendy

Premium

Intramolecular Huisgen‐Type Cyclization of Platinum‐Bound Pyrylium Ions with Alkenes and Subsequent Insertion into a Benzylic CH Bond

Author(s) -

Oh Chang Ho,

Lee Ji Ho,

Lee Su Jin,

Kim Jae Il,

Hong Chang Seop

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200802425

Subject(s) - chemistry , alkene , platinum , cycloaddition , intramolecular force , carbene , medicinal chemistry , double bond , side chain , stereochemistry , catalysis , photochemistry , polymer chemistry , organic chemistry , polymer

Access granted : The platinum‐catalyzed cyclization of enynals 1 , which contain an additional alkene bond in their side chain, through a [3+2] cycloaddition to give tetracyclic platinum–carbene complexes A was followed by CH insertion at the δ position to afford highly complex products 2 . These polycyclic compounds and related products of the title transformation are extremely difficult to access by other means.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research