Premium
Branched‐Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group
Author(s) -
Grünanger Christian U.,
Breit Bernhard
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200802296
Subject(s) - hydroformylation , regioselectivity , catalysis , alkene , chemistry , group (periodic table) , organic chemistry , rhodium
Phosphinites do the trick and work as reversibly bound catalyst‐directing groups in catalytic amounts to allow for the highly regioselective hydroformylation of homoallylic alcohols with terminal and internal alkene functions in favor of the branched product.