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[1,5]‐Hydride Transfer/Cyclizations on Alkynyl Fischer Carbene Complexes: Synthesis of 1,2‐Dihydroquinolinyl Carbene Complexes and Cascade Reactions
Author(s) -
Barluenga José,
FañanásMastral Martín,
Aznar Fernando,
Valdés Carlos
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200802268
Subject(s) - carbene , hydride , chemistry , cascade , medicinal chemistry , transition metal carbene complex , photochemistry , organic chemistry , catalysis , hydrogen , chromatography
Trigger happy : A new cascade process initiated by an unprecedented [1,5]‐hydride transfer/cyclization of ortho ‐aminophenyl alkynyl Fischer carbene complexes leads to the formation of new 1,2‐dihydroquinolinyl carbene complexes and 5,6‐dihydrophenantridine derivatives (see scheme).