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Iron‐Catalyzed CC Bond Formation by Direct Functionalization of CH Bonds Adjacent to Heteroatoms
Author(s) -
Li Zhiping,
Yu Rong,
Li Haijun
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200802215
Subject(s) - heteroatom , surface modification , molecule , chemistry , combinatorial chemistry , catalysis , organic chemistry , ring (chemistry)
Iron/oxidant can do : Heteroatom‐containing molecules are abundant in natural products, pharmaceuticals, and materials. It is highly desirable to synthesize these molecules and their derivatives by direct CH functionalization. The novel title reaction provides a simple and efficient method to construct such molecules by using 1,3‐dicarbonyl compounds (see scheme).