Synthetic Access to the Chlorocyclopentane Cores of the Proposed Original and Revised Structures of Palau′amine | Zendy

Bultman Michael S. | Zendy; Ma Jun | Zendy; Gin David Y. | Zendy

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Synthetic Access to the Chlorocyclopentane Cores of the Proposed Original and Revised Structures of Palau′amine

Author(s) -

Bultman Michael S.,

Ma Jun,

Gin David Y.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200801969

Subject(s) - sigmatropic reaction , computer science , sequence (biology) , amine gas treating , core (optical fiber) , beckmann rearrangement , information retrieval , combinatorial chemistry , stereochemistry , chemistry , organic chemistry , telecommunications , oxime , biochemistry

Core knowledge : The synthesis of the functionalized cores of both the originally proposed and revised structures of palau′amine have been achieved (see structures). A Diels–Alder/[3,3]‐sigmatropic rearrangement sequence and a Beckmann rearrangement enable the stereocontrolled formation of the highly congested cores.

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