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The [Ti 12 Nb 6 O 44 ] 10− Ion—A New Type of Polyoxometalate Structure
Author(s) -
Ohlin C. André,
Villa Eric M.,
Fettinger James C.,
Casey William H.
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200801883
Subject(s) - polyoxometalate , cluster (spacecraft) , mass spectrometry , crystallography , ion , materials science , chemistry , inorganic chemistry , analytical chemistry (journal) , catalysis , organic chemistry , chromatography , computer science , programming language
An extraordinarily useful cluster to detail reaction pathways in water might have been obtained in form of [N(CH 3 ) 4 ] 10 [Ti 12 Nb 6 O 44 ], a polyoxometalate with a central cavity. This compound is soluble in a range of solvents and has been characterized by ESI mass spectrometry and X‐ray crystallography (see picture; [ 1 ]=[Ti 12 Nb 6 O 44 ] 10− ).