The [Ti 12 Nb 6 O 44 ] 10−  Ion—A New Type of Polyoxometalate Structure | Zendy

Ohlin C. André | Zendy; Villa Eric M. | Zendy; Fettinger James C. | Zendy; Casey William H. | Zendy

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The [Ti 12 Nb 6 O 44 ] 10− Ion—A New Type of Polyoxometalate Structure

Author(s) -

Ohlin C. André,

Villa Eric M.,

Fettinger James C.,

Casey William H.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200801883

Subject(s) - polyoxometalate , cluster (spacecraft) , mass spectrometry , crystallography , ion , materials science , chemistry , inorganic chemistry , analytical chemistry (journal) , catalysis , organic chemistry , chromatography , computer science , programming language

An extraordinarily useful cluster to detail reaction pathways in water might have been obtained in form of [N(CH 3 ) 4 ] 10 [Ti 12 Nb 6 O 44 ], a polyoxometalate with a central cavity. This compound is soluble in a range of solvents and has been characterized by ESI mass spectrometry and X‐ray crystallography (see picture; [ 1 ]=[Ti 12 Nb 6 O 44 ] 10− ).

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