A Linear, Anionic Dimetalloborylene Complex | Zendy

Braunschweig Holger | Zendy; Burzler Michael | Zendy; Dewhurst Rian D. | Zendy; Radacki Krzysztof | Zendy

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A Linear, Anionic Dimetalloborylene Complex

Author(s) -

Braunschweig Holger,

Burzler Michael,

Dewhurst Rian D.,

Radacki Krzysztof

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200801848

Subject(s) - dimethoxyethane , lithium (medication) , ion , chemistry , medicinal chemistry , reduction (mathematics) , inorganic chemistry , stereochemistry , organic chemistry , mathematics , geometry , electrode , electrolyte , endocrinology , medicine

A boryl anion with a Mn‐imum of fuss : The reduction of 1 with lithium sand yielded the first anionic dimetalloborylene complex 2 , which is totally separated from its counter cation [Li(dme) 3 ] + (dme=1,2‐dimethoxyethane). The anion reacts with MeI to give the corresponding methylborylene complex [{(η 5 ‐C 5 H 4 Me)(OC) 2 Mn} 2 (μ‐BMe)].

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