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Multiple Functions of Ionic Liquids in the Synthesis of Three‐Dimensional Low‐Connectivity Homochiral and Achiral Frameworks
Author(s) -
Zhang Jian,
Chen Shumei,
Bu Xianhui
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200801838
Subject(s) - ionic liquid , ionic bonding , chemistry , content (measure theory) , computer science , crystallography , chemical physics , ion , organic chemistry , mathematics , mathematical analysis , catalysis
One foot in the door : In the self‐assembly of a homochiral or achiral low‐connectivity metal–dicarboxylate framework, an ionic liquid (shown: EMIm‐Es) undergoes either complete entrapment, partial (cation‐only), or no entrapment. The structure type depends on the ionic liquid and whether a structure‐directing agent is used.