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Catalytic Hydrochlorination of Unactivated Olefins with para ‐Toluenesulfonyl Chloride
Author(s) -
Gaspar Boris,
Carreira Erick M.
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200801760
Subject(s) - simple (philosophy) , catalysis , scheme (mathematics) , cobalt , chemistry , chloride , computer science , organic chemistry , mathematics , philosophy , mathematical analysis , epistemology
A simple solution to a long‐standing problem: The hydrochlorination of unactivated alkenes, which is shown in the Scheme, is catalyzed by simple cobalt complexes and proceeds under very mild conditions. The ready availability of all components and the ease of execution render the method very convenient.