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Borylene Transfer under Thermal Conditions for the Synthesis of Rhodium and Iridium Borylene Complexes
Author(s) -
Braunschweig Holger,
Forster Melanie,
Kupfer Thomas,
Seeler Fabian
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200801756
Subject(s) - iridium , rhodium , chemistry , photochemistry , stereochemistry , organic chemistry , catalysis
Borylene transfer reactions to [(η 5 ‐C 5 R 5 )M(CO) 2 ] (M=Rh, R=H; M=Ir, R=Me) using [(OC) 5 MoBN(SiMe 3 ) 2 ] as a borylene source proceed at room temperature and generate terminal rhodium and iridium borylene complexes (see scheme). Iridium complex 1 was characterized by X‐ray crystallography.