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Homodinuclear Ruthenium Catalysts for Dimer Ring‐Closing Metathesis
Author(s) -
Tzur Eyal,
BenAsuly Amos,
Diesendruck Charles E.,
Goldberg Israel,
Lemcoff N. Gabriel
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200801626
Subject(s) - ruthenium , closing (real estate) , ring closing metathesis , dimer , catalysis , metathesis , ring (chemistry) , computer science , olefin metathesis , salt metathesis reaction , combinatorial chemistry , chemistry , political science , organic chemistry , polymerization , law , polymer
Two ring or not to ring : Novel diruthenium olefin metathesis catalysts show a tendency to avoid oligomerization and favor cyclic dimerization when the distances between the ruthenium centers and between the diene extremities match (see scheme).