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Functionalized Coordination Space in Metal–Organic Frameworks
Author(s) -
Fischer Roland A.,
Wöll Christof
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200801612
Subject(s) - metal organic framework , component (thermodynamics) , sorption , modular design , materials science , organic component , space (punctuation) , metal , nanotechnology , chemistry , computer science , chemical engineering , organic chemistry , engineering , metallurgy , physics , adsorption , thermodynamics , operating system
Two significant advances in the development of metal–organic frameworks (MOFs) are perfluoro MOFs (see structure) with an outstanding volumetric gas uptake and hysteretic sorption of dihydrogen. The modular synthesis of functional MOFs involves a two‐component framework, in which one component is an integral component of the framework and the other can be exchanged after formation of the matrix.