Premium
Reactivity of a Terminal Chromium Borylene Complex towards Olefins: Insertion of a Borylene into a CH Bond
Author(s) -
Braunschweig Holger,
Dewhurst Rian D.,
Herbst Thomas,
Radacki Krzysztof
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200801579
Subject(s) - chemistry , moiety , reactivity (psychology) , terminal (telecommunication) , stereochemistry , medicine , telecommunications , alternative medicine , pathology , computer science
Borylene insertion : Irradiation of the terminal borylene complex [(OC) 5 CrBN(SiMe 3 ) 2 ] at room temperature in the presence of 3,3‐dimethyl‐1‐butene leads to insertion of the aminoborylene moiety into the olefinic CH bond and formation of a vinylborane complex (see structure).
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom