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Reactivity of a Terminal Chromium Borylene Complex towards Olefins: Insertion of a Borylene into a CH Bond
Author(s) -
Braunschweig Holger,
Dewhurst Rian D.,
Herbst Thomas,
Radacki Krzysztof
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200801579
Subject(s) - chemistry , moiety , reactivity (psychology) , terminal (telecommunication) , stereochemistry , medicine , telecommunications , alternative medicine , pathology , computer science
Borylene insertion : Irradiation of the terminal borylene complex [(OC) 5 CrBN(SiMe 3 ) 2 ] at room temperature in the presence of 3,3‐dimethyl‐1‐butene leads to insertion of the aminoborylene moiety into the olefinic CH bond and formation of a vinylborane complex (see structure).