Premium
Concomitant and Controllable Chiral/Racemic Polymorphs: From Achirality to Isotactic, Syndiotactic, and Heterotactic Chirality
Author(s) -
Li XinZhi,
Li Mian,
Li Zhen,
Hou JinZhang,
Huang XiaoChun,
Li Dan
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200801481
Subject(s) - tacticity , chirality (physics) , supramolecular chemistry , supramolecular chirality , resolution (logic) , materials science , stereochemistry , chemistry , crystallography , crystal structure , computer science , organic chemistry , physics , chiral symmetry , artificial intelligence , polymerization , nambu–jona lasinio model , polymer , quantum mechanics , quark
Making a resolution : A unique example of chiral/racemic polymorphs, which are obtained from achiral components (see picture), illustrates the evolution in chirality from partial to complete spontaneous resolution, and the phenomenon of supramolecular isotactic, syndiotactic, and heterotactic chirality.