Polyimido Uranium(IV) Clusters: Imidometalates with an M 7 (μ 3 ‐N) 6 (μ 2 ‐N) 6  Core Analogous to the Anderson‐Type Polyoxometalate Motif | Zendy

Berthet JeanClaude | Zendy; Thuéry Pierre | Zendy; Ephritikhine Michel | Zendy

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Polyimido Uranium(IV) Clusters: Imidometalates with an M 7 (μ 3 ‐N) 6 (μ 2 ‐N) 6 Core Analogous to the Anderson‐Type Polyoxometalate Motif

Author(s) -

Berthet JeanClaude,

Thuéry Pierre,

Ephritikhine Michel

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200801420

Subject(s) - polyoxometalate , uranium , chemistry , metal , pyridine , crystallography , cluster (spacecraft) , inorganic chemistry , catalysis , physics , medicinal chemistry , nuclear physics , organic chemistry , computer science , programming language

NU clusters : Novel imido uranium(IV) clusters involving four or seven metal centers have been obtained from the reaction of UCl 4 and [{PhNMg(thf)} 6 ] in thf or pyridine (see core structure; U yellow, N purple, Cl green, O red). The aggregation is strongly dependent on the nature of the solvent.

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