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Tungsten‐Mediated Activation of a Pb II N bond: A New Route to Tungsten–Lead Triple Bonds
Author(s) -
Filippou Alexander C.,
Weidemann Nils,
Schnakenburg Gregor
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200801331
Subject(s) - tungsten , triple bond , amide , chemistry , crystallography , bond , lead (geology) , polymer chemistry , business , organic chemistry , double bond , geology , geomorphology , finance
A WPb bond is present in the hydrido plumbylidyne complex trans ‐[H(PMe 3 ) 4 WPb(2,6‐Trip 2 C 6 H 3 )], which is formed by an unprecedented PbN activation reaction of {Pb(2,6‐Trip 2 C 6 H 3 )NMe 2 } 2 , the first structurally characterized organolead(II) amide (see picture for molecular structure). Trip=2,4,6‐ i Pr 3 C 6 H 2 .
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