Reaction Dynamics of the Decaniobate Ion [H  x  Nb 10 O 28 ] (6− x )−  in Water | Zendy

Villa Eric M. | Zendy; Ohlin C. André | Zendy; Balogh Edina | Zendy; Anderson Travis M. | Zendy; Nyman May D. | Zendy; Casey William H. | Zendy

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Reaction Dynamics of the Decaniobate Ion [H x Nb 10 O 28 ] (6− x )− in Water

Author(s) -

Villa Eric M.,

Ohlin C. André,

Balogh Edina,

Anderson Travis M.,

Nyman May D.,

Casey William H.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200801125

Subject(s) - polyoxometalate , dissociation (chemistry) , isotopes of oxygen , ion , cluster (spacecraft) , chemistry , stable isotope ratio , isotope , physics , crystallography , nuclear physics , computer science , nuclear chemistry , catalysis , biochemistry , organic chemistry , programming language

The nanometer‐size title cluster is unique in that it reacts slowly enough in water that one can simultaneously observe steady‐state oxygen‐isotope exchanges and dissociation pathways (see scheme; O red, Nb green), leading to conceptual advances in both geochemistry and polyoxometalate chemistry.

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