Synthesis of the Prototypical Cyclic Metallocene Triad: Mixed‐Valence Properties of [(FeCp) 3 (trindenyl)] Isomers | Zendy

Santi Saverio | Zendy; Orian Laura | Zendy; Donoli Alessandro | Zendy; Bisello Annalisa | Zendy; Scapinello Marco | Zendy; Benetollo Franco | Zendy; Ganis Paolo | Zendy; Ceccon Alberto | Zendy

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Synthesis of the Prototypical Cyclic Metallocene Triad: Mixed‐Valence Properties of [(FeCp) 3 (trindenyl)] Isomers

Author(s) -

Santi Saverio,

Orian Laura,

Donoli Alessandro,

Bisello Annalisa,

Scapinello Marco,

Benetollo Franco,

Ganis Paolo,

Ceccon Alberto

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200801124

Subject(s) - chemistry , metallocene , valence (chemistry) , triad (sociology) , fusion , crystallography , spectral line , infrared spectroscopy , stereochemistry , organic chemistry , polymerization , psychology , linguistics , philosophy , physics , astronomy , psychoanalysis , polymer

The “ fusion” of three ferrocenes into a rigid cyclic array produces the syn , syn , anti and syn , syn , syn isomers of [(FeCp) 3 (trindenyl)] (see picture), the cations of which display different mixed‐valence properties, namely multiple intervalence‐transfer (IT) absorptions appear in the near‐IR/IR spectra for the syn , syn , anti isomer, while a single band appears in the visible/near‐IR spectrum for the syn , syn , syn isomer.

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