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Simple NUF 3 and PUF 3 Molecules with Triple Bonds to Uranium
Author(s) -
Andrews Lester,
Wang Xuefeng,
Lindh Roland,
Roos Björn O.,
Marsden Colin J.
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200801120
Subject(s) - uranium , molecule , simple (philosophy) , chemistry , triple bond , materials science , organic chemistry , double bond , metallurgy , philosophy , epistemology
UN‐beatable? Laser‐ablated uranium atoms activate NF 3 and PF 3 to form the NUF 3 and PUF 3 molecules containing novel terminal nitride and phosphide functional groups. These molecules are identified from matrix infrared spectra and theoretical methods. The NUF 3 molecule contains the strongest triple bond to uranium in a ternary compound.
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