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A Crystallizable f‐Element Tuck‐In Complex: The Tuck‐in Tuck‐over Uranium Metallocene [(C 5 Me 5 )U{μ‐η 5 :η 1 :η 1 ‐C 5 Me 3 (CH 2 ) 2 }(μ‐H) 2 U(C 5 Me 5 ) 2 ]
Author(s) -
Evans William J.,
Miller Kevin A.,
DiPasquale Antonio G.,
Rheingold Arnold L.,
Stewart Timothy J.,
Bau Robert
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200801062
Subject(s) - metallocene , uranium , radiochemistry , chemistry , materials science , polymerization , organic chemistry , metallurgy , polymer
Long sought structural data on an f‐element tuck‐in complex have been obtained for the title compound 1 that contains the first example of both tuck‐in and tuck‐over bonding in a ligand derived from C 5 Me 5 − by metalation (see scheme).
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