Predicting Enthalpy of Vaporization of Ionic Liquids: A Simple Rule for a Complex Property | Zendy

Verevkin Sergey P. | Zendy

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Predicting Enthalpy of Vaporization of Ionic Liquids: A Simple Rule for a Complex Property

Author(s) -

Verevkin Sergey P.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200800926

Subject(s) - vaporization , ionic liquid , enthalpy , thermodynamics , enthalpy of vaporization , simple (philosophy) , standard enthalpy change of formation , ionic bonding , chemistry , ion , position (finance) , computational chemistry , organic chemistry , physics , philosophy , epistemology , catalysis , finance , economics

A simple additive approach based on the empirical formula has been developed to calculate the enthalpy of vaporization of an ionic liquid, which is separated into a main contribution from the constituent elements (regardless of their position in the cation or anion) and an auxiliary contribution (correction) due to structural peculiarities, such as the presence of CF 3 groups or a cyclic structure.

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