The Homoleptic Sandwich Anion [Co(P 2 C 2  t Bu 2 ) 2 ] − : A Versatile Building Block for Phosphaorganometallic Chemistry | Zendy

Wolf Robert | Zendy; Ehlers Andreas W. | Zendy; Slootweg J. Chris | Zendy; Lutz Martin | Zendy; Gudat Dietrich | Zendy; Hunger Michael | Zendy; Spek Anthony L. | Zendy; Lammertsma Koop | Zendy

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The Homoleptic Sandwich Anion [Co(P 2 C 2 t Bu 2 ) 2 ] − : A Versatile Building Block for Phosphaorganometallic Chemistry

Author(s) -

Wolf Robert,

Ehlers Andreas W.,

Slootweg J. Chris,

Lutz Martin,

Gudat Dietrich,

Hunger Michael,

Spek Anthony L.,

Lammertsma Koop

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200800813

Subject(s) - homoleptic , block (permutation group theory) , ion , chemistry , electrophile , anthracene , computer science , organic chemistry , combinatorics , mathematics , metal , catalysis

A sandwich recipe: Treatment of the anthracene complex [Co(η 4 ‐C 14 H 10 ) 2 ] − with t BuCP leads to the new diphosphacyclobutadiene sandwich anion 1 , which can be converted into the unprecedented phosphaorganometallic complexes 2 – 4 upon treatment with different electrophiles (see scheme).

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