Controlling the Activation of White Phosphorus: Formation of Phosphorous Acid and Ruthenium‐Coordinated 1‐Hydroxytriphosphane by Hydrolysis of Doubly Metalated P 4 | Zendy

Barbaro Pierluigi | Zendy; Di Vaira Massimo | Zendy; Peruzzini Maurizio | Zendy; Seniori Costantini Stefano | Zendy; Stoppioni Piero | Zendy

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Controlling the Activation of White Phosphorus: Formation of Phosphorous Acid and Ruthenium‐Coordinated 1‐Hydroxytriphosphane by Hydrolysis of Doubly Metalated P 4

Author(s) -

Barbaro Pierluigi,

Di Vaira Massimo,

Peruzzini Maurizio,

Seniori Costantini Stefano,

Stoppioni Piero

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200800723

Subject(s) - ruthenium , chemistry , hydrolysis , white phosphorus , phosphorus , phosphorous acid , yield (engineering) , ligand (biochemistry) , phosphorus acid , catalysis , organic chemistry , materials science , biochemistry , receptor , metallurgy

Successfully tamed : When coordinated to two {CpRu(PPh 3 ) 2 } moieties, white phosphorus (P 4 ) reacts selectively with a large excess of water to yield phosphorous acid (H 3 PO 3 ) and the previously unknown 1‐hydroxytriphosphane (PH(OH)PHPH 2 ), which is stabilized as a bridging ligand by coordination to the ruthenium moieties (see scheme).

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