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Monodentate, N‐Heterocyclic Carbene‐Type Coordination of 2,2′‐Bipyridine and 1,10‐Phenanthroline to Iridium
Author(s) -
Conejero Salvador,
Lara Patricia,
Paneque Margarita,
Petronilho Ana,
Poveda Manuel L.,
Serrano Oracio,
Vattier Florencia,
Álvarez Eleuterio,
Maya Celia,
Salazar Verónica,
Carmona Ernesto
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200800705
Subject(s) - iridium , carbene , denticity , chemistry , reactivity (psychology) , phenanthroline , ligand (biochemistry) , bipyridine , 2,2' bipyridine , medicinal chemistry , stereochemistry , combinatorial chemistry , crystallography , organic chemistry , catalysis , crystal structure , medicine , biochemistry , alternative medicine , receptor , pathology
Unusual Carbenes : 2,2′‐Bipyridine and 1,10‐phenanthroline are capable of coordinating to iridium as monodentate N‐heterocyclic carbene ligands stabilized by NH⋅⋅⋅N bonding. This reactivity leads to complexes like 1 and their analogues with 2 as the carbene ligand. [Ir]: [hydrotris(3,5‐dimethylpyrazolyl)borate]iridium.