Monodentate, N‐Heterocyclic Carbene‐Type Coordination of 2,2′‐Bipyridine and 1,10‐Phenanthroline to Iridium | Zendy

Conejero Salvador | Zendy; Lara Patricia | Zendy; Paneque Margarita | Zendy; Petronilho Ana | Zendy; Poveda Manuel L. | Zendy; Serrano Oracio | Zendy; Vattier Florencia | Zendy; Álvarez Eleuterio | Zendy; Maya Celia | Zendy; Salazar Verónica | Zendy; Carmona Ernesto | Zendy

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Monodentate, N‐Heterocyclic Carbene‐Type Coordination of 2,2′‐Bipyridine and 1,10‐Phenanthroline to Iridium

Author(s) -

Conejero Salvador,

Lara Patricia,

Paneque Margarita,

Petronilho Ana,

Poveda Manuel L.,

Serrano Oracio,

Vattier Florencia,

Álvarez Eleuterio,

Maya Celia,

Salazar Verónica,

Carmona Ernesto

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200800705

Subject(s) - iridium , carbene , denticity , chemistry , reactivity (psychology) , phenanthroline , ligand (biochemistry) , bipyridine , 2,2' bipyridine , medicinal chemistry , stereochemistry , combinatorial chemistry , crystallography , organic chemistry , catalysis , crystal structure , medicine , biochemistry , alternative medicine , receptor , pathology

Unusual Carbenes : 2,2′‐Bipyridine and 1,10‐phenanthroline are capable of coordinating to iridium as monodentate N‐heterocyclic carbene ligands stabilized by NH⋅⋅⋅N bonding. This reactivity leads to complexes like 1 and their analogues with 2 as the carbene ligand. [Ir]: [hydrotris(3,5‐dimethylpyrazolyl)borate]iridium.

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