Copper‐Catalyzed Arylation of Nucleophiles by Using Butadienylphosphines as Ligands: Mechanistic Insight | Zendy

Kaddouri Hamid | Zendy; Vicente Virginie | Zendy; Ouali Armelle | Zendy; Ouazzani Fouad | Zendy; Taillefer Marc | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Copper‐Catalyzed Arylation of Nucleophiles by Using Butadienylphosphines as Ligands: Mechanistic Insight

Author(s) -

Kaddouri Hamid,

Vicente Virginie,

Ouali Armelle,

Ouazzani Fouad,

Taillefer Marc

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200800688

Subject(s) - nucleophile , ligand (biochemistry) , copper , catalysis , combinatorial chemistry , chemistry , scale (ratio) , computer science , organic chemistry , physics , biochemistry , receptor , quantum mechanics

Worth diene for : The butadienylphosphine L (see scheme), obtained on a large scale from a new synthetic method, is an efficient ligand in Ullmann‐type copper‐catalyzed arylation reactions. The use of this phosphorus ligand made it possible to follow the reaction by 31 P NMR spectroscopy and thus to propose a mechanism for the Ullmann reaction.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research