Total Synthesis of Polyoxygenated Cembrenes | Zendy

Tietze Lutz F. | Zendy; Brazel C. Christian | Zendy; Hölsken Sören | Zendy; Magull Jörg | Zendy; Ringe Arne | Zendy

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Total Synthesis of Polyoxygenated Cembrenes

Author(s) -

Tietze Lutz F.,

Brazel C. Christian,

Hölsken Sören,

Magull Jörg,

Ringe Arne

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200800626

Subject(s) - domino , metathesis , key (lock) , stereoselectivity , closing (real estate) , ring closing metathesis , computer science , alkylation , stereochemistry , content (measure theory) , chemistry , mathematics , organic chemistry , political science , operating system , law , catalysis , polymerization , polymer , mathematical analysis

A convergent approach for the stereoselective construction of polyoxygenated cembrenes is reported. Key steps in the synthesis are an asymmetric domino multicomponent allylation, a modified Myers α‐alkylation, and a ring‐closing metathesis.

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