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An Iron Nitride Complex
Author(s) -
Vogel Carola,
Heinemann Frank W.,
Sutter Jörg,
Anthon Christian,
Meyer Karsten
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200800600
Subject(s) - nitride , carbene , tris , content (measure theory) , characterization (materials science) , chemistry , computer science , crystallography , materials science , nanotechnology , organic chemistry , mathematics , catalysis , biochemistry , mathematical analysis , layer (electronics)
High on nitride : Discrete iron nitride complexes stabilized by N‐anchored tris(carbene) ligands have been synthesized (see picture). These high‐valent Fe IV N complexes are stable at room temperature, which allows their full spectroscopic and—for the first time—crystallographic characterization.