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Carbocycle Synthesis through Facile and Efficient Palladium‐Catalyzed Allylative De‐aromatization of Naphthalene and Phenanthrene Allyl Chlorides
Author(s) -
Lu Shirong,
Xu Zhanwei,
Bao Ming,
Yamamoto Yoshinori
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200800529
Subject(s) - phenanthrene , aromatization , naphthalene , palladium , chemistry , ring (chemistry) , catalysis , medicinal chemistry , organic chemistry
Ring of truth : The palladium‐catalyzed reaction of allyltributylstannane with naphthalene or phenanthrene derivatives bearing an allyl chloride group proceeds smoothly to provide de‐aromatized products with unique structures (see scheme). These products are very stable and can be used as intermediates to give fused‐ring systems.