Intermolecular Hydroarylation of Unactivated Olefins Catalyzed by Homogeneous Platinum Complexes | Zendy

Luedtke Avery T. | Zendy; Goldberg Karen I. | Zendy

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Intermolecular Hydroarylation of Unactivated Olefins Catalyzed by Homogeneous Platinum Complexes

Author(s) -

Luedtke Avery T.,

Goldberg Karen I.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200800524

Subject(s) - platinum , catalysis , olefin fiber , intermolecular force , ethylene , chemistry , homogeneous , benzene , catalytic cycle , solvent , aryl , homogeneous catalysis , medicinal chemistry , combinatorial chemistry , organic chemistry , polymer chemistry , molecule , mathematics , alkyl , combinatorics

Designing catalysts : The five‐coordinate platinum(IV) complex A and the platinum(II) trans complex B act as precatalysts for the hydroarylation of unactivated olefins. The catalytic cycle features an aryl–olefin insertion at Pt II and a CH bond activation of the arene solvent as key steps. The Pt II cis complex C has been observed in hydroarylation reactions of ethylene with benzene.

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