Stable Five‐ and Six‐Coordinate Cobalt(III) Complexes with a Pentadentate Bispidine Ligand | Zendy

Comba Peter | Zendy; Kerscher Marion | Zendy; Lawrance Geoffrey A. | Zendy; Martin Bodo | Zendy; Wadepohl Hubert | Zendy; Wunderlich Steffen | Zendy

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Stable Five‐ and Six‐Coordinate Cobalt(III) Complexes with a Pentadentate Bispidine Ligand

Author(s) -

Comba Peter,

Kerscher Marion,

Lawrance Geoffrey A.,

Martin Bodo,

Wadepohl Hubert,

Wunderlich Steffen

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200800515

Subject(s) - denticity , pyridine , chemistry , ligand (biochemistry) , dissociation (chemistry) , cobalt , amine gas treating , stereochemistry , photochemistry , crystallography , medicinal chemistry , inorganic chemistry , crystal structure , organic chemistry , receptor , biochemistry

I am ligand : A pentadentate bispidine ligand with two tertiary amine and three pyridine donors stabilizes the uncommon intermediate‐spin electronic configuration of Co III ( S =1; see picture: C gray, N blue, O red, Co violet). Dissociation of the monodentate coligand yields a catalytically active pentacoordinate complex.

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