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Sc 3 N@C 80 ‐Ferrocene Electron‐Donor/Acceptor Conjugates as Promising Materials for Photovoltaic Applications
Author(s) -
Pinzón Julio R.,
PlonskaBrzezinska Marta E.,
Cardona Claudia M.,
Athans Andreas J.,
Gayathri S. Shankara,
Guldi Dirk M.,
Herranz M. Ángeles,
Martín Nazario,
Torres Tomas,
Echegoyen Luis
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200800473
Subject(s) - ferrocene , photovoltaics , cycloaddition , chemistry , electrochemistry , covalent bond , materials science , crystallography , photovoltaic system , organic chemistry , catalysis , ecology , electrode , biology
Intriguing materials for photovoltaics : The first trimetallic nitride endohedral metallofullerene covalently connected to a donor group is efficiently synthesized in a 1,3‐dipolar cycloaddition reaction. Exclusive formation of the [5,6]‐regioisomer in the isolated N ‐methyl‐2‐ferrocenyl‐ I h ‐Sc 3 N@C 80 ‐fulleropyrrolidine is confirmed by NMR spectroscopy and electrochemistry (see picture).