A Core–Corona Hierarchical Manganese Oxide and its Formation by an Aqueous Soft Chemistry Mechanism | Zendy

Portehault David | Zendy; Cassaig Sophie | Zendy; Nassif Nadine | Zendy; Baudrin Emmanuel | Zendy; Jolivet JeanPierre | Zendy

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A Core–Corona Hierarchical Manganese Oxide and its Formation by an Aqueous Soft Chemistry Mechanism

Author(s) -

Portehault David,

Cassaig Sophie,

Nassif Nadine,

Baudrin Emmanuel,

Jolivet JeanPierre

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200800331

Subject(s) - context (archaeology) , birnessite , supercapacitor , aqueous solution , template , nanotechnology , lamellar structure , manganese , oxide , precipitation , materials science , porosity , nanostructure , chemistry , chemical engineering , electrochemistry , manganese oxide , organic chemistry , electrode , geology , composite material , paleontology , meteorology , engineering , physics

No template and no organic medium are needed for the low‐temperature, one‐pot aqueous route to layered manganese oxides with a hierarchical core–corona architecture (see picture). Particle formation occurs by a two‐step precipitation process with two different kinetics.

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