A Coordinatively Linked Yb Metal–Organic Framework Demonstrates High Thermal Stability and Uncommon Gas‐Adsorption Selectivity | Zendy

Ma Shengqian | Zendy; Wang XiSen | Zendy; Yuan Daqiang | Zendy; Zhou HongCai | Zendy

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A Coordinatively Linked Yb Metal–Organic Framework Demonstrates High Thermal Stability and Uncommon Gas‐Adsorption Selectivity

Author(s) -

Ma Shengqian,

Wang XiSen,

Yuan Daqiang,

Zhou HongCai

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200800312

Subject(s) - ytterbium , selectivity , adsorption , thermal stability , metal , metal organic framework , chemistry , ion , inorganic chemistry , chemical engineering , materials science , organic chemistry , doping , optoelectronics , catalysis , engineering

Narrow pores for high selectivity : The ytterbium metal–organic framework PCN‐17, which contains coordinatively (through SO 4 2− ions) linked, doubly interpenetrated (8,3)‐nets (see picture), is stable up to 480 °C and exhibits selective adsorption of H 2 and O 2 over N 2 and CO.

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