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A Coordinatively Linked Yb Metal–Organic Framework Demonstrates High Thermal Stability and Uncommon Gas‐Adsorption Selectivity
Author(s) -
Ma Shengqian,
Wang XiSen,
Yuan Daqiang,
Zhou HongCai
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200800312
Subject(s) - ytterbium , selectivity , adsorption , thermal stability , metal , metal organic framework , chemistry , ion , inorganic chemistry , chemical engineering , materials science , organic chemistry , doping , optoelectronics , catalysis , engineering
Narrow pores for high selectivity : The ytterbium metal–organic framework PCN‐17, which contains coordinatively (through SO 4 2− ions) linked, doubly interpenetrated (8,3)‐nets (see picture), is stable up to 480 °C and exhibits selective adsorption of H 2 and O 2 over N 2 and CO.