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A Metallacryptand‐Based Manganese(II)–Cobalt(II) Ferrimagnet with a Three‐Dimensional Honeycomb Open‐Framework Architecture
Author(s) -
Pardo Emilio,
Cangussu Danielle,
Dul MarieClaire,
Lescouëzec Rodrigue,
Herson Patrick,
Journaux Yves,
Pedroso Emerson F.,
Pereira Cynthia L. M.,
Muñoz M. Carmen,
RuizGarcía Rafael,
Cano Joan,
Amorós Pedro,
Julve Miguel,
Lloret Francesc
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200800208
Subject(s) - ferrimagnetism , manganese , honeycomb , cobalt , honeycomb structure , lithium (medication) , magnet , condensed matter physics , spintronics , ferromagnetism , chemistry , computer science , crystallography , physics , topology (electrical circuits) , materials science , combinatorics , mathematics , quantum mechanics , inorganic chemistry , geometry , magnetization , psychology , magnetic field , organic chemistry , psychiatry , composite material
Building a three‐dimensional magnet : The manganese(II)‐mediated self‐assembly of a ferromagnetically coupled dicobalt(II) metallacryptand provides the first example of an oxamato‐bridged heterobimetallic ferrimagnet with a three‐dimensional honeycomb open‐framework structure hosting linear arrays of water‐bridged lithium(I) guests (see picture; mpba=1,3‐phenylenebis(oxamato)).